Refractory Materials Supplier, Refractory Products, Magnesia Refractory Material, Furnace Refractory - CX Refractories

Refractory Materials Supplier, Refractory Products, Magnesia Refractory Material, Furnace Refractory - CX Refractories

Refractory Materials Supplier, Refractory Products, Furnace Refractory

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Ladle with refractory materials are used

refractory materials

Common types of ladle refractories:
(1) Clay refractory brick, clay brick A12O3 content is generally between 30% -50%, the price is low. Mainly used for ladle permanent layer and ladle bottom.
(2) high alumina brick. Brick A12O3 content of 50% -80%, mainly for the working layer ladle.
(3) wax stone brick. The refractory supplier brick is characterized by high SiO2 content. Generally more than 80%, anti-erosion than the clay brick and the integrity of the good, and not hanging residue. Commonly used in the ladle wall and package at the end.
(4) Zircon brick. The brick is mainly used for ladle slag line parts. Brick ZrO2 content is generally between 60% -65%.
(5) Magnesia carbon bricks. The brick is mainly used for ladle slag line parts, especially for multi-furnace continuous casting occasions. Brick MgO content is generally about 76%, carbon content of 15% -20%. It is characterized by small erosion of slag, erosion resistance, good resistance to spalling.
(6) aluminum-magnesium castables. The castable is mainly used for the steel body, and is characterized in that, under the action of molten steel, MgO and A12O3 in the castable react with each other to form aluminum oval spinel, thereby improving the thermal shock resistance of the lining.
(7) aluminum-magnesium carbon brick. This brick is developed on the basis of aluminum-magnesium castable ladle lining, long service life.
(8) Do not burn brick. At present, the materials used in ladle firing bricks can be made into corresponding unburned brick. Its characteristics are relatively simple production process, the price is lower. Brick itself has a certain mechanical strength and erosion resistance, easy construction masonry.
If the ladle itself is also used for refining, you can also choose MgO-Cr2O3-A10O3 series and magnesia carbon brick refractory, are: magnesia-chrome brick, magnesia-chrome-aluminum brick, dolomite brick.
In the content of ink material used for ladle lining brick, it is best to apply a layer of anti-oxidation coating on its surface to prevent burning in the package, the lining surface oxidation loose, affecting its service life.

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Refractory materials for glass furnaces

Refractory materials

There are three key drivers behind the evolution of refractories: maintaining improved glass quality; economic requirements on glass kilns to make kilns run longer and impact after pure oxygen combustion systems.
The word "current" can be read in months or even weeks as the computer industry in the electronics industry changes. When it comes to the development and application of refractories in the glass industry, it can easily be read as five or ten years. Based on this notion of time, we will recall that there has been a change in the discussion of the "current" area (more conservatively) in the latter area.
There are three major driving forces behind the development of refractory materials. The first glass manufacturer typically needs to improve glass quality in order to maintain it at least. The second glass kiln economy required a longer kiln operation cycle and a third pure oxygen combustion system with impact. These three requirements usually determine the choice of improved refractories when repairing the kiln. These impetuses have also prompted the glass manufacturer to use the furnace with improved fire-resistant products for maintenance and repair, as well as the introduction of new technologies for a wide range of maintenance runs.
Melting-cast alumina bricks have been melting pool top this part of the establishment of its application, the main melting high-quality glass pure oxygen combustion furnace was applied. Prior to the advent of pure oxygen combustion technology, only beta alumina bricks were used to melt pool superstructure and no melt cast alumina bricks were used on top of the melting pool. Today, both β-alumina and α-β alumina melt-cast products are used to produce color TV (screen cone), float glass and borosilicate glass pure oxygen combustion furnace some or all of the roof. Melt-cast AZS bricks can typically be used at 1600 ° C or 1650 ° C (depending on the glazing), while furnace tops with fused alumina are successfully operated at 1700 ° C. This gives glass manufacturers greater flexibility when creating refractory glass.
For many years, melt-cast AZS roofs have successfully undergone a cooling and reheating test to enable them to use multiple operating cycles. There is now a bit of experience in the successful implementation of top cooling and reheating of fused-alumina roofing, demonstrating an economically viable life when they use two or more cycles of operation. The results of fused alumina furnace roof observation (thermal observation and shutdown) show that these materials are both chemically and mechanically stable. This was the earliest observation of this type of masonry study since there was neither a fused alumina reference nor the empirical basis of its roof application.
High-chromium refractory products used to be mainly used to enhance the glass furnace, and a small amount used in insulation glass pool furnace. High chrome bricks are increasingly being used by some soda lime glass furnaces. Its main use has not only been limited to all or part of the flow hole, but also for the end wall and to a limited extent for the filler brick. For high chrome brick components, they are potentially dangerously colored, so that high-chromium products are often not compatible with very "white" glass. In the initial period this product was mainly used for colored glass, but high chromium products have also been successfully used in transparent container glass furnaces. The use of high-chromium glass furnaces depends largely on the design of the liquid hole, the cooling of the liquid hole, the daily production of the furnace, and the operation of the furnace. A glass manufacturer may use high-chrome bricks for the entire cover plus the melting tank end wall. High Chromite brickwork liquid caves offer the potential to increase kiln life because this material provides at least twice as much resistance to most glass as molten AZS bricks. However, some design parameters differ from those of fused AZS bricks and need to be discussed with the supplier.

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Principle of Selection of Refractories for Cement Kiln

refractory material

Preheat zone and decomposition zone
The temperature of these two places is relatively low,  refractory material requiring brick lining of the thermal conductivity is small, good wear resistance, in this area from raw materials, fuel sulfuric acid base and chlorinated alkali began to evaporate, in the kiln condensation and enrichment, and infiltration brick internal. Ordinary clay brick and alkali reaction to form kaolinite and garnet, so that the brick surface crisp, brick body expansion caused by cracking peeling. And containing Al2O3 25% ~ 28% and SiO2 65% ~ 70% of the alkali-resistant or alkali-resistant insulation brick at a certain temperature and alkali reaction, the brick surface immediately formed a layer of high viscosity glaze layer, to prevent the Peeling, but this brick can not resist the use of more than 1200 ℃ temperature. So the preheating zone is generally combined with high alumina refractory bricks, anti-peeling high alumina bricks or resistant to alkali brick.
Decomposition with the general use of anti-peeling good high alumina brick, silicon brick in the performance is better than the anti-peeling good high alumina brick, life than peeling off the high alumina brick about twice as high, but the price is higher, kiln The tail feed should be made of anti-crusted silicon carbide castable.
Transition zone and firing zone
Transition zone kiln leather is unstable, require kiln lining resistance to climate change ability, good thermal shock resistance, thermal conductivity is small, wear. Foreign recommended magnesium aluminum spinel brick, but the thermal conductivity of the brick, the cylinder temperature is high, the relative heat consumption is large, is not conducive to reducing energy consumption. Domestic silicon Mo brick thermal conductivity is small, wear, its performance to a certain extent, comparable with imported materials.
Burning zone with high temperature, intense chemical reaction, requiring brick lining anti-clinker erosion, anti-SO3, CO2 capacity. Foreign generally use magnesium aluminum spinel brick, but the brick hanging kiln skin is more difficult, and dolomite brick thermal shock resistance is not good, easy to hydrate; foreign magnesium iron spinel brick in the hanging kiln skin effect is better , But the cost is too high. The use of new low-chromium perovskite composite spinel brick use is better.
Cooling belt and kiln mouth
Cooling zone and kiln temperature as high as 1400 ℃ or so, the temperature fluctuations, clinker grinding and air erosion are very serious. Requirements of brick lining of the thermal conductivity is small, wear resistance, thermal shock resistance; good thermal shock resistance of alkaline bricks, such as spinel brick or high alumina brick for cooling zone. Foreign generally recommended the use of spinel brick, but the spinel brick thermal conductivity, and wear resistance is not good. Most of the domestic use in recent years, silicon-resistant brick and anti-peeling good wear-resistant brick.
Kiln parts of the use of good resistance to thermal shock castable. Such as: wear-resistant heat-resistant high-alumina brick or steel fiber toughened castables and low-cement high-alumina refractory castable, but the kiln temperature is very high in the large kiln is the use of ordinary, or steel fiber toughening Of the corundum castable.
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Refractory materials for industrial furnaces

Refractory materials for industrial furnaces

Refractory materials for industrial furnaces:
High-strength lightweight clay high alumina brick, high-aluminum foam brick, poly light brick, light mullite insulation brick, heavy carburizing refractory brick, diatomaceous earth insulation brick, pearlite refractory bricks. All kinds of pit furnace, box furnace, carburizing furnace, trolley furnace, vibration furnace, steel chain plate furnace, mesh belt furnace, crucible furnace, push burning furnace, vacuum furnace, salt bath furnace with light, Heavy standard fire bricks, shaped bricks. Electric corundum furnace tube, silicon carbide furnace tube, high alumina furnace tube.
Electric radiant tube with corundum, high aluminum insulator, plug cover clip.
Electric furnace furnace with corundum silicon carbide brick, radiant furnace floor. Textile machinery singeing machine with a variety of specifications of silicon carbide fire bricks, honeycomb panels, masonry with a variety of high temperature adhesives.
Fire mud, anti-carburized mud, aluminum silicate fiber cotton, aluminum silicate fiber felt, aluminum silicate fiber board.

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Characteristic Refractory Material Mud Mixing Method

Characteristics of refractory material mud mixture method is to produce special refractory products, in particular the use of gypsum injection molding, casting and injection molding molding of the mud slurry f operation method is the ingredients of various refractory raw materials, enhancers, Suspending agent, admixture and 30 ~ 40% of the clean water, while adding a wear-resistant lining in the ball mill (mixing mill), after a certain period of mixing fine grinding, made for the production of mud slurry. In the process of making mud, according to the characteristics of materials and mud pouring their own requirements, to control the density and pH of the mud.
Mud mixing method used by the main equipment are ball mill, air compressor, wet iron, mud pump, vacuum degasser and so on.
Paraffin and resin-based binder, at room temperature for the solid refractory materials (or into a sticky), at room temperature, especially law mixture, must be used to increase the method of heating.
The use of hot casting process, the use of paraffin as a binder. Due to the melting point of paraffin in the 60-80 <€, in the first paraffin heated to 100T or more and have good mobility, and then the fine powder raw materials added to the liquid paraffin, the mixing after mixing, made of slurry Wax cake for hot die casting.
The main mixing equipment for heating the mixture is a heated mixing mixer.

The use of refractory materials in the metallurgical industry

refractory materials

Insulation Refractory material refers to refractory materials with high porosity, low bulk density and low thermal conductivity. It features a porous structure (typically 40% to 85% porosity) and high heat insulation.

Insulation refractory material used as the furnace insulation layer, lining or insulation layer, can save fuel costs. More types, mainly light refractory products, heat insulation and refractory materials and their products.

Lightweight refractory products

The main light of silicon refractory brick, light clay brick, light high alumina brick and alumina hollow ball products. Usually the weight of light refractory products is usually 0.6-1.2g / cm3, the use of temperature is usually 900 ~ 1350 Yi. Alumina hollow ball products can be used in the following long-term use.

2 refractory fiber and its products

Refractory fiber is a fibrous refractory material, is a new type of high efficiency insulation products. The main production method of refractory fiber is melt blown method, high speed centrifugation and colloid method.

Refractory fiber The main types of aluminum silicate refractory fiber, zirconium aluminum silicate refractory fiber, high purity high alumina refractory fiber, polycrystalline mullite fiber, alumina fiber, zirconia fiber and so on. In addition for low-temperature insulation of the slag cotton, glass fiber and so on. Refractory fiber products are refractory fiber as the primary raw material, processed by the various blankets, felt, board, rope, paper and other high-temperature insulation materials.

Refractory fiber products with small bulk density, low thermal conductivity, thermal stability and resistance to mechanical sensation. Refractory fiber products only 0.1 ~ 0.2g / cm3 bulk density. With fire-resistant fiber products do kiln lining, heat loss is small, saving fuel, heating up fast, especially for intermittent work furnace. In addition, fire-resistant fiber also has a soft, easy processing, construction and other characteristics. At present, the production and use of refractory fiber has been rapid development, metallurgical and other industrial enterprises demand for refractory fiber more and more urgent. After the use of refractory fiber, the energy saving effect is obviously improved.

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Basic properties of refractory material for steel making

As we all know that China refractory is of various kinds and is widely used and also of great importance in steel industry. The following are some refractories commonly used in steel industry summarized by Changxing Refractory engineers.

(1) Refractories for converter
Magnesia carbon refractory brickis used for furnace cap, tapping converter mouth, before and after the surface, weld pool and bottom; high strength magnesia carbon brick is used for trunnion and slag line. Usually the MgO content in magnesia carbon brick is 70 ~ 75%, graphite is 16 ~ 20%, bulk density is 2.8 ~ 2.9 g/cm3, compressive strength is 25 ~ 30 MPa. The elements of high strength magnesia carbon brick are the same elements as magnesia carbon fire brick, but its compressive strength should be 30 ~ 42 MPa.

(2) Refractories for electric furnace
Furnace hearth, furnace slope and molten pool are overall rammed with magnesia clinker, or constructed with magnesia brick which is made of magnesia carbon brick and tar asphalt; high-quality MgO-C bricks is used for hot and slag line area; magnesia brick and magnetite chrome brick are used for tapping hole and the two sides of furnace door; high alumina bricks or high alumina brick clay brick are used for furnace cover.

(3) Refractories for UHP EAF
For permanent lining of ultra high power EAF, using magnesium stone; for furnace doorjamb, using magnesia chrome brick; for slag line, eccentric bottom and molten pool, using magnesia refractory firebrick; for hot spots, furnace wall and tapping hole, using magnesite carbon brick; for furnace cover, using high alumina brick; for tapping hole filler, using high ankerite filling material.

According to the working conditions of various steel furnaces, it can be proved that the refractory materials for furnace working circumstance is very bad. Therefore, whatever refractory for smelting are used, it must possess the following properties.
(1) High temperature resistant and high refractoriness.
(2) Erosion and erosion resistance to high temperature molten steel and slag.
(3) The steelmaking furnace works discontinuously, thus requires refractory material with good thermal shock resistance and spalling resistance.
(4) High mechanical strength, can withstand impact of furnace tilting and furnace charge loading with no damage.

Article source:
Basic properties of refractory material for steel making
E-mail:sales8@chinaelong.com

Measures to solve refractory brick damage

After analyzing mechanism and causes of refractory brick damage, then we can take corresponding countermeasure and measure according to these reasons to reduce the damage, so as to achieve purpose of extending service life of refractory brick.    According to the explanation of our technical staff, we know the cause of refractory brick physical damage and chemical damage ash and kiln skin erosion thin, mechanical damage and the refractory brick masonry quality. That is to say to extend the service life of refractory bricks in burning zone, in addition to select suitable suppliers, shall be laid a good grasp of building quality, maintain the skin at the kiln during operation. The specific measures taken are as the following two aspects.

On the one hand, maintaining the quality of laying refractory brick.

1. Cement ratio and dilute the appropriate thick. Specific detection method is easy to spread the cement shop into the brick, and can not flow. Too thick is not easy to spread too thin, is easy to flow; two is in a brick on the fire clay, pressure on another brick slightly strong kneading, and then lift up the brick body, the brick below belt, that the proper proportion of cement.

2. The front of refractory brick to be close to the cylinder. Between the brick and the cylinder body cannot pad fireclay and other debris. In the pool of fireclay brick, in front stretcher rectangular to leave 1 to 2 cm position does not stand in the cement, upward pressure brick, end close 

to the cylinder pressure to the fireclay, knead move, make cement covered the face brick, a small amount of excess cement extruded from the bricks and the small end of the big two, brick end matter stick cylinder. Brick joints cannot be greater than 1.5mm. Check brick facet, row not up, wrapping phenomenon.

3. The top tight top bar. In half of the circumference of the masonry, with top carry to brick top tight, rotary kiln bricks on the other half of the week, when the top bar must be the top tight. Some cube material should be laid between brick and the top bar, to avoid damage of refractory brick. Method to check whether the roof top bar tension is, when the top bar with the rotation of the cylinder to check the cylinder top brick not flagging lock position, if the sagging phenomenon, in the kiln and kiln refractory during the relative displacement caused by mechanical damage to the refractory brick.

For the other aspect, click here for the next industry news.

On the other hand, hanging up and maintain kiln coating. We suggest taking the following measures. 

1. For kiln operation training and guidance. Before firing, give the workers a training about kiln operation. Clearly pointed out that in any case, hang up and maintain good kiln crust is mainly the responsibility of kiln. At the same time about operating method under different conditions to them, in the actual operation, according to the kiln to give operation guidance and comments in a timely manner, to carry out technical exchanges between operations, and constantly improve the technological level of operation.

2. Coal spraying pipe should be put in the proper position which tending to the lowr side is the best.

3. Improving technology level.

4. Proper proportioning solution: the quantity of liquid phase resistance is suitable in 22-24%. Too low is not easy to hang kiln skin, too much can narrow the range of sintering temperature, silicate minerals reduce, not conducive to the operation and improve the quality of clinker.